I have a serial interface and an old RS232 based OBDII interface.
Any suggestions as to how I capture data from that interface ?
RS232 OBD-2 interfaces either contain some MCU (like ELM323) or are pass-through, but then support only ISO9141.
Try sending "ATI" to the interface. If you get back only "ATI", then it's pass-through. If you get back identification information (like for modem), then it's ELM-32x.
Anyway, I would recommend getting some USB OBD2 interface, such as
http://www.obdtester.com/elm-usb. Serial interfaces usually do not support CAN-BUS and have problems with timing. There is a lot of programs that work with it,
http://www.obdtester.com/obdtester and open-source pyOBD:
http://www.obdtester.com/pyobd