Calibration to be accurate is not an easy thing to do. Approximations are possible by using some kitchen chemistry to make CO2 from Baking Soda/Vinegar, but you need to some how purge the system of CO2 to get a 0 concentration. Maybe make O2 using hydrogen peroxide/piece of uncooked ground beef. You can bubble the pure 02 into an inverted cup long enough to insure all other gases are gone. The use a known weight of NaHCO3 to make a known amount of CO2. You could also use whip cream cans to purge gases out and replace with all Nitrous Oxide, then blend in CO2. Or a battery and water to make H2 and O2 (cathode/anode respectively if my e-chem serves me correctly)
Not so easy to calibrate....and be careful with the pure O2....it makes things burn really well...Most of these sensors are calibrated by purchasing premixed gas blends.
and in both cases above, don't let the pressure build up.....the chemistry happens until its done no matter what you do.